Airplanes and passenger trains must meet strict safety requirements, including those related to fire protection. This calls for materials that are flame-retardant, lightweight, robust, and scalable. Working with their industry partner Elantas, Empa researchers have now succeeded for the first time in making such a material—a composite—fully recyclable.
“No flying machine will ever fly from New York to Paris,” aviation pioneer Orville Wright once said. What even the visionary Wright brothers considered impossible is now a reality—thanks, in part, to new materials that make modern aircraft and engines possible in the first place. In the more than 100 years since the Wrights’ first flight attempts, aviation has not only become more powerful but, fortunately, also significantly safer. The materials used in aircraft construction must meet the strictest safety requirements, including fire safety standards. At the same time, they must be lightweight and mechanically robust—and, increasingly, recyclable as well.
“Bringing all these properties together under one roof is a challenge,” explains Empa researcher Sabyasachi Gaan from the “Advanced Fibers” laboratory. “For example, when you make a material flame-retardant, you always end up altering its other properties as well.” Gaan and his team, together with their industry partner Elantas—part of the German specialty chemicals group ALTANA—took on this challenge in a project supported by Innosuisse. Their focus was on a specific composite material used in the interior construction of airplanes and trains, such as for the floor of the passenger cabin.
Epoxy Is Becoming More Sustainable
The material is a multilayer “sandwich.” At its center is a honeycomb structure made of aramid, a heat-resistant plastic. This sturdy, lightweight core is covered on top and bottom with several flat-woven layers of glass or carbon fibers. Epoxy resin serves as the binder, as it does in many composite materials. Normally, this polymer cannot be recycled either chemically or thermally—in other words, it can neither be melted down nor dissolved. “Composites containing epoxy currently end up in landfills or are incinerated,” says Gaan.
This is exactly where the Empa researchers have an ace up their sleeve. They have developed an additive for epoxy resin that makes the material flame-retardant—and recyclable at the same time. If this phosphorus-containing molecule is added to the epoxy during production, the material can be softened and reshaped under certain conditions after it has cured—a process known as thermomechanical recycling, which was previously impossible for epoxy.
All components recovered
In the Innosuisse project, however, the partners pursued a different goal: the complete recycling of the composite material. With the right solvent and a little heat, the “sandwich” can be broken down again into its individual components: the honeycomb structure and the woven fibers. Aramid honeycombs in particular—but also carbon fibers—are relatively expensive. Recycling them is therefore also economically attractive. “In principle, it’s also possible to recover the epoxy resin itself from the solution. We plan to tackle that in future projects,” says Gaan.
The recyclable epoxy resin was developed at Empa. Working with Elantas, the researchers have now explored its potential for industrial application for the first time. “Our material complies with fire safety regulations and achieves nearly the same beneficial mechanical properties as conventional epoxy,” says Gaan. “But for the first time, it allows for the complete recycling of the composite material.”
The project partners are satisfied with how the project is progressing. The next step is to further scale up production and recycling. “For the aerospace industry, it is crucial to combine fire protection, lightweight construction, and recyclability. This epoxy composite system demonstrates that this is now possible for the first time,” says Fiorenzo Lenzi, Head of the Aerospace/Ballistic Product Line at Elantas.
At the same time, Sabyasachi Gaan and his team are already conducting research into further applications for the recyclable, flame-retardant plastic, such as in the energy sector and the construction industry. The scientist emphasizes that the fact a material has come this far is also thanks to basic research. “Before we can work on the applications, we need to have a very good understanding of the material’s properties.” The Wright brothers would likely agree with him. For, as Wilbur Wright wrote in a letter to engineer Octave Chanute in 1900, “It is possible to fly without engines, but not without knowledge and skill.”
Innovations for Switzerland—Thanks to New Materials
About 70% of all innovations are based on new materials. Outstanding materials research and technology development are therefore essential for an innovation hub like Switzerland. This is exactly what Empa, the materials research institute of the ETH Domain, has stood for—for more than 120 years. Here, interdisciplinary teams are constantly creating new innovations, such as biodegradable batteries and computer components, drones that can dive into water while in flight, digital twins of entire cities, novel therapies against antibiotic-resistant pathogens, alternative materials for problematic substances like PFAS, and much more. Through countless industrial collaborations and spin-offs, Empa’s vision—“Materials and Technologies for a Sustainable Future”—is thus carried out into the Swiss economy and society.